Account

Table 1 Polycondensation of TSH and Zn(OAc) ₂

From: Organic-sulfur-zinc hybrid nanoparticle for optical applications synthesized via polycondensation of trithiol and Zn(OAc)₂

Run	Monomer	Yield (%)^a	M_n(M_w/M_n)^b	Zn/S^c
1	OTSH	48	7400 (1.4)	0.29
2	BTSH	64	-^d	0.40
3	HTSH,	62	-^d	0.37
4	IATSH	68	-^d	0.45
5	EHTSH	62	-^d	0.71

Conditions: TSH 0.200 mmol, Zn(OAc)₂ 0.300 mmol, dioxane 5.0 mL, 60°C, 24 h, N₂. ^aIsolated yield after precipitation with methanol. ^bEstimated by GPC (THF, polystyrene standard). ^cEstimated using EDX (ratios calculated as averages of ten spots). ^dNot measurable due to poor solubility.

Back to article page