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Table 1 Binding energies (in eV) of the XPS peaks and VBM for GaN, AlN, GaN/AlN, and AlN/GaN samples

From: Band offsets of non-polar A-plane GaN/AlN and AlN/GaN heterostructures measured by X-ray photoemission spectroscopy

Sample

State

Binding energy(eV)

 

GaN

Ga 3d

19.70 ± 0.03

Ga-N

 

20.70 ± 0.03

N2s

VBM

2.06 ± 0.03

 

AlN

Al 2p

73.85 ± 0.01

Al-N

 

75.05 ± 0.01

Al-O

VBM

2.74 ± 0.09

 

GaN/AlN

Al 2p

73.36 ± 0.01

Al-N

Ga 3d

18.56 ± 0.03

Ga-N

19.96 ± 0.03

N2s

AlN/GaN

Al 2p

73.43 ± 0.01

Al-N

74.63 ± 0.01

Al-O

Ga 3d

19.23 ± 0.03

Ga-N

20.23 ± 0.03

N2s

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