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Table 1 Calculated particle sizes, deconvoluted emission spectra, and PLQYs of various QDs dispersed in water

From: Impurity Location-Dependent Relaxation Dynamics of Cu:CdS Quantum Dots

Sample

Sizea/nm

Sizeb/nm

Sizec/nm

d spacing d/nm

E g e/eV

λ em f/nm

λ 1

λ 2

λ 3

QY/%

CdS

2.3

2.8

3.2

0.336

3.01

501

465 ± 28(12%)g

504 ± 47(40%)

569 ± 68(48%)

9.1

d-Cu:CdS

2.5

2.6

3.4

0.364

2.91

632

499 ± 54(14%)

631 ± 67(76%)

749 ± 56(10%)

5.3

e-Cu:CdS

2.6

2.8

3.5

0.362

2.89

635

506 ± 67(17%)

634 ± 67(71%)

740 ± 63(12%)

3.4

a-Cu:CdS

2.6

2.7

3.8

0.354

2.79

646

647 ± 79(93%)

788 ± 57(7%)

0.5

 
  1. aAverage value of the major and the minor axes calculated from HRTEM images
  2. bAverage diameter calculated from an XRD pattern
  3. cDiameter calculated from an absorption spectrum using the Brus equation
  4. dAverage distance between adjacent (111) planes, observed from an XRD pattern
  5. eBand-gap energy in the unit of nm
  6. fWavelength at the emission maximum
  7. gArea percentage

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