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Structural Peculiarities of Ion-Conductive Organic-Inorganic Polymer Composites Based on Aliphatic Epoxy Resin and Salt of Lithium Perchlorate

  • 1, 2,
  • 1, 3Email author,
  • 1,
  • 1,
  • 1, 3,
  • 3,
  • 3 and
  • 2
Nanoscale Research Letters201712:423

  • Received: 28 December 2016
  • Accepted: 12 June 2017
  • Published:


The article is concerned with hybrid amorphous polymers synthesized basing on epoxy oligomer of diglycide aliphatic ester of polyethylene glycol that was cured by polyethylene polyamine and lithium perchlorate salt. Structural peculiarities of organic-inorganic polymer composites were studied by differential scanning calorimetry, wide-angle X-ray spectra, infrared spectroscopic, scanning electron microscopy, elemental analysis, and transmission and reflective optical microscopy. On the one hand, the results showed that the introduction of LiClO4 salt into epoxy polymer leads to formation of the coordinative metal-polymer complexes of donor-acceptor type between central Li+ ion and ligand. On the other hand, the appearance of amorphous microinclusions, probably of inorganic nature, was also found.


  • Epoxy resin
  • Lithium perchlorate salt
  • Glass transition temperature
  • Amorphous composite
  • Coordinative complexes


  • 81.07.Pr
  • 62.23.St


Liquid electrolytes are commonly used in lithium or lithium-ion batteries at room temperature with the ionic conductivity from 10−3 to 10−2 S/cm [1, 2].

It would be useful if the batteries could work at higher temperatures, since it will be no need to use a separate cooling circuit at the system level, or such need will be significantly reduced [3]. However, high temperatures create difficulties because of quick degradation of liquid electrolytes [3]. In addition, there are two main problems that hinder the development of liquid electrolytes. First, formation of the lithium dendrites on electrodes leads to serious danger due to the potential possibility of internal short circuits. Second, the electrochemical instability of the lithium electrodes causes an insignificant life cycle of batteries during repeated processes of charging/discharging [4].

In addition, the first generation of battery prototypes, which used liquid electrolytes, have a high risk of leaks affecting on the reliability of a device [1]. Safety is one of the most pressing issues related to the further progress in development of the next-generation batteries. That makes solid electrolytes one of the most promising candidates for replacement of flammable and potentially dangerous liquid electrolytes [5].

Solid polymer electrolytes (SPE) have been used in different applications as the ion conductors in various electrochemical devices such as lithium batteries, ultracapacitors, fuel cells, and solar cells [6]. Rechargeable lithium and lithium-ion batteries play an important role on the market of electrochemical energy storage devices, since they are widely used for charging of portable electronic devices and for autonomous controlling devices [2]. Therefore, recently, the development of new solid polymer electrolytes was an important objective, since optimal balance between high ionic conductivity and technological conditions of material has not been still achieved [7, 8]. SPE have such properties as good compatibility with electrodes, low self-discharging rate, easy processing for various shapes and sizes, lack of leakage, flexibility, and self-sufficiency for form changes during charge-discharge cycles [710].

Polyethylene oxide (PEO) [11, 12] is one of the mostly studied oligomers, which are used for SPE creation due to the effective coordination of metal ions in it because of the optimum distance and orientation of ether oxygen atoms in its molecular chains [12]. The disadvantage of PEO is amorphous-crystalline structure [4, 13, 14] that leads to the conductivity through the amorphous area of a polymer only [11, 15] above the glass transition temperature T g [6, 12, 16], and as a result, PEO has low ionic conductivity at room temperature because of the presence of high crystalline phase [4, 14, 17].

Nowadays, as a rule, solid polymer electrolytes include inorganic salts dissolving in oligomers which, in their turn, form a solid matrix with the ionic conductivity [10, 12, 18, 19]. Added salt serves as a source of ions and contributes their movement along the polymer chains, so that it plays the crucial role in ion transport in polymer electrolytes [16]. Hereby, concentration and mobility of ions are significant parameters affecting the conductivity in polymer electrolytes [14, 17]. Understanding of mechanism of the ion transport in a polymer requires the study of ion-ion and ion-polymer interactions that is of great interest [10, 14]. Many studies of ion transport in polymer electrolytes have been conducted using various types of cations such as Na+, Li+, Ag+, and Mg+ [20]. However, the composites based on lithium salts are preferably studied, because the Li+ cations are the smallest and can easily move in a polymer matrix [17, 20]. Another important characteristic is thermal stability of ions and their inertness to the cell components [21].

High ionic conductivity can be achieved by increasing the salt concentration in polymer [6]; however, the authors [9] have shown that conductivity of the composites based on PEO is limited by certain value of a salt concentration. At higher salt concentration, the conductivity decreases because of formation of the ion complexes, which, in turn, causes reduction of the ionic mobility and the number of charge carriers [10].

For application as electrolytes, polymers should have certain properties, such as amorphousness, the presence of ether oxygen in their structure, low glass transition temperature, high-dimensional stability, mechanical strength, and the ability to form thin films [9, 18]. One of the suitable materials that satisfies these requirements is aliphatic epoxy oligomer, namely, the diglycide aliphatic ester of polyethylene glycol. It has an identical to polyethylene oxide chain structure, however, is amorphous and is able to dissolve the high concentration of lithium perchlorate salt similarly to PEO.

Therefore, the aim of the present work is the synthesis of solid amorphous polymer composites based on aliphatic epoxy oligomer and the study of influence of lithium perchlorate salts on their structure.


Materials and Synthesis

The epoxy oligomer (diglycide aliphatic ester of polyethylene glycol (DEG-1)) and lithium perchlorate (LiClO4) salt were used for synthesis of ion-conductive epoxy polymer composites. These components were previously pre-dried in vacuum at 80 °C during 24 h. After drying, the salt was dissolved in the DEG-1 oligomer. Solutions of DEG-1-LiClO4 were prepared with LiClO4 content from 0 to 50 phr of DEG-1. 10 phr of polyethylene polyamine (PEPA) hardener has been used as a curing agent for synthesis of the composites.

Thermal characteristics were studied by differential scanning calorimetry (DSC) with TA Instruments DSC Q2000 in the temperature range from −70 to +150 °C with the heating rate of 10 °C/min. Glass transition temperature (T g) was determined from the DSC curves at the second heating. The experimental error of determination of the glass transition temperatures was ±1 °C.

The electrical and dielectric characteristics were investigated by the broadband dielectric analyzer “Novocontrol Alpha” with Novocontrol Quatro Cryosystem (Novocontrol Technologies, Montabaur, Germany) that was equipped with a two-electrode circuit, in the frequency range from 10−1 to 107 Hz and the temperature range from −60 to +200 °C. The voltage applied to a sample was equal to 0.5 V. The test samples had a diameter of 20 mm and a thickness of 0.5 mm and were previously coated by aluminum layer under vacuum. The obtained data was analyzed using the software “Novocontrol WinDeta 3.8.”

Structural organization and features of macromolecular ordering of the synthesized polymer systems were investigated by wide-angle X-ray spectra (WAXS) using the X-ray diffractometer DRON-4.7. X-ray optical scheme was performed by Debye-Scherer method on passing the primary beam through the polymer sample polymer using CuK α emission (λ = 1.54 Å) that was made monochromatic by Ni filter. The investigations were carried out by automatic step scanning in the range of scattering angles (2θ) from 2.6° to 40°, and the exposure time was 5 s.

Infrared (IR) spectroscopic studies have been performed using spectrometer with Fourier transformation “Tensor-37” from Bruker Corp. in the range of wave numbers 600°–3800° cm−1. According to the passport of the device, the relative measurement error is <2%.

The morphological features of the synthesized composites were studied using method of the reflective optical microscopy (ROM) by Unicorn NJF 120A polarization microscope at polarization angles 0°–90°. Microphotographs analysis was performed using Carl Zeiss Imaging Solutions AxioVision V4.7.1 software.

Structural features of the synthesized composites have been studied using methods of the electron microscopy (SEM) by JEOL 100-CX II transmission electron microscope, equipped with scanning system. Elemental analysis of inclusions was performed using analytical complex consisting of a scanning electron microscope JEOL JSM-35CF, and X-ray spectrometer with dispersive in energy X-ray quanta (Model INCA Energy-350 from “Oxford Instruments”). An important feature of such electron microprobe analysis is its locality: maximum size of the excitation area is 2 μm. According to the morphological characteristics and the chemical composition basing on the energy dispersive spectral analysis, the automatic separation of inclusions on types (elemental composition) and measuring of their sizes has been carried out. The results have been analyzed using a special program for quantitative phase distribution and inclusion investigation. All results are presented in weight percent. The experimental error was 0.1%.

WAXS, IR, ROM, and SEM studies and elemental analysis were carried out at the temperature T = 20 ± 2 °C.

Results and Discussion

Analysis of the DSC studies as well as of the dielectric and electrical investigations of the synthesized composites with lithium perchlorate salt content from 0 to 20 phr was previously presented in our paper [22]. Further widening of LiClO4 content (from 0 to 50 phr) maintains linear increase of glass transition temperature T g from −10 to 64 °C (Fig. 1a). That can be a result of electrostatic interactions between lithium cations Li+ and the macromolecular chain of DEG-1 with forming of coordinative complexes, which are accompanied by displacement of electron density of the oxygen atoms and their partial polarization. It is reflected in a substantial reduction of segmental mobility of DEG-1 chains within the formed complexes that is shown up in the increase of glass transition temperature of polymer matrix.
Fig. 1
Fig. 1

Thermal and electrical characteristics of composites. a Dependence of glass transition temperature T g (a) and conductivity σ at 60 and 200 °C (b) on LiClO4 salt content

Figure 1b shows the change of conductivity σ with growth of LiClO4 content in composite. At low temperature (60 °C), the maximal value of σ is reached at 10 phr of salt and the σ value of composite with 20 phr of LiClO4 is equal to that in pure DEG-1. At high temperature (200 °C), the σ values are three orders of magnitude higher with maximum at 15 phr of LiClO4. Such character of conductivity dependence on LiClO4 content can be explained by existence of two opposite competitive processes. First, growth of salt content in composite gives the increase of carrier number and the raise of conductivity. Second, growth of T g reflects the restriction of DEG-1 molecular movements which reduces the carriers mobility. At higher temperatures, the raising of molecular movements compensates this mechanism and conductivity becomes essentially higher.

Analysis of the wide-angle X-ray diffraction patterns of the systems has shown that all of them are amorphous (Fig. 2). The average value of the period (d) of a short-range molecular ordering of DEG-1/PEPA internodal molecular segments located in the polymer volume can be calculated using Bragg equation:
Fig. 2
Fig. 2

The WAXS studies of the DEG-1/LiClO4 systems. The wide-angle X-ray diffraction patterns of a lithium perchlorate salt LiClO4 and systems with the different salt content (shown near curves)

$$ d= l{\left(2 \sin {\theta}_m\right)}^{-1} $$

where λ is the wavelength of the characteristic X-ray emission (λ = 1.54 Å for CuK α emission) and it equals to 4.44 Å.

However, the introduction of LiClO4 salt having a crystalline structure into the epoxy resin is accompanied by changes in the diffraction pattern. That is evidenced by the presence of subtle diffraction peak of the diffuse type at 2θ m  ≈ 12.2° on the background of the amorphous halo, which is similar to the angular position of the DEG-1 at 2θ m  ≈ 20.0° (d ≈ 4.39 Å). This diffraction peak characterizes the existence of metal-polymer complexes of the donor-acceptor type, in our case, between central ions (Li+) and ether oxygen of the epoxy chains in the intermolecular volume of the epoxy resin, and this confirms the assumptions made by the analysis of DSC data. Basing on the angular position of this diffraction peak in composite with 50 phr of LiClO4, the average Bragg distance d between the molecular chains coordinated by cations Li+ is 4.30 Å.

Structure of the polymer composites has been investigated by means of infrared spectroscopy. The main absorption bands of LiClO4, DEG-1, and PEPA with relevant groups are presented in Table 1. These absorption bands were interpreted in accordance with [2325], respectively.
Table 1

Interpretation of the absorption band IR spectra of LiClO4, DEG-1, and PEPA




Wave number, cm−1

Group, type fluctuations

Wave number, cm−1

Group, type fluctuations

Wave number, cm−1

Group, type fluctuations


–OH, ν (a water)


–OH, ν


NH2 + NH, ν




–CH2–, ν asym


–CH2–, ν asym

1086, 1113, 1146

ClO4 , ν asym


–CH2–, ν sym


–CH2–, ν sym


ClO4 , ν sym


–CH2–, δ

1641, 1585

NH2 + NH, δ


ClO4 (not associated with Li+)


CH2–, δ


CH2–, δ


Epoxy group, ν sym


CH2–, δ


C–O–C, ν


C–N–C, ν

910, 856

Epoxy group, ν asym

ν valence vibration, ν sym and ν asym valence symmetric and asymmetric vibrations, δ bending vibration

As one can see, the characteristic absorption bands of epoxies’ ring are absent in the spectra (Fig. 3, 0 phr LiClO4 content) that indicates the complete curing of epoxy component. These absorption bands are also absent in the IR spectra (Fig. 3, 5–50 phr) of the cured composites. The absorption bands in the range of wave numbers 1300–1520 and 1000–1190 cm−1, which respectively correspond to fluctuations of –CH2– and (C–O–C and C–NC) groups, expand and shift to the low-frequency region with LiClO4 content increase. It is known that this can be associated with the formation of coordination bonds between Li+ cations and ClO4 anions and polymer chains [26, 27]. It is generally accepted that Li+ cations can easily form complexes with polyethylene ether bonds [23, 24, 2730] as well as with polyamines [31]. The absorption band at 1637 cm−1 in the IR spectrum of LiClO4 indicates its undissociated state (Table 1) [23, 24]. It should be noted that this band in the IR spectra of 5–50 samples is absent. This indicates that the pure (undissociated) form of LiClO4 in the composites is not contained. In accordance to this, in Fig. 4 the possible ion-dipole interactions of Li+ ion with the ether bond of polyethylene oxide fragment and OH group of the disclosed epoxy ring of DEG-1 (Fig. 4a–d) and with secondary amine group of PEPA (Fig. 4e), with secondary or tertiary amine group and ether bond simultaneously (Fig. 4e–g), are shown. As an example of coordinated ClO4 ion, Fig. 4h represents the scheme of this anion interaction with positively charged carbon atom that is located near the electronegative oxygen atom.
Fig. 3
Fig. 3

The IR spectra of the composites. The infrared spectroscopy of the systems with the different lithium perchlorate salt content (the numbers near curves)

Fig. 4
Fig. 4

ah Schemes of complexes. Complexes which possibly exist in the systems LiClO4/DEG-1/PEPA

It should be noted that in the sample with addition of 5 phr lithium perchlorate and after solidification, a new absorption band at 864 cm−1 appears in its IR spectrum, which maintains in the samples with 10–50 phr salt content. Considering that the most of the absorption bands of metal complexes are located in the low-frequency region [32], it is obvious that this absorption band is associated to complexes involving LiClO4. The interaction of PEO and LiClO4 is widely studied in literature, and in presented materials, the absorption band around 860 cm−1 is absent [23, 24, 2730]. Probably, this band refers to formation of lithium amino-complex, which presence influences the fluctuations of methylene groups located nearby. That is confirmed by appearance of a new absorption band in the IR spectrum of composite with 5 phr of LiClO4 at 1525 cm−1 (Fig. 3), which is shifted to the low-frequency region with increasing of the salt content up to 50 phr. In accordance to [26], this is due to the increasing number of coordination bonds. Important to note that when film samples with 5–50 phr of LiClO4 were crushed into a powder and molded in the KBr tablets, the described absorption bands at ≤1525 and 860–864 cm−1 disappeared, since crushing leads to destruction of the weak coordination bonds. That also confirms the coordination nature of these bands. As an example, Fig. 5 shows the IR spectra of the samples with 5 and 30 phr of LiClO4 contents.
Fig. 5
Fig. 5

The IR spectra (in tablets of KBr). The IR spectra of the composites with different LiClO4 content (marked by numbers near curves)

Generally, the increasing quantity of LiClO4 leads to the increase of the coordination bonds, which reduce mobility of macromolecular chains [28]. Figure 3 shows a gradual decrease in intensity of the absorption bands associated with valence fluctuations of OH–, NH–, and –CH2– groups. At the destruction of coordination bonds in the samples molded in the KBr tablets, these valence bonds are clearly manifested (Fig. 5).

In addition to the coordination bonds, other important factors which influence on the structure of the obtained composites should be indicated. Thus, the reaction between DEG-1 and PEPA in the presence of LiClO4 occurs more completely, apparently (to a certain limit of salt), since it is known that LiClO4 is an effective aminolysis catalyst of oxiranes ring [33]. Another structure-forming factor can be realized as a net of hydrogen bonds, including ones with the participation of ClO4 ions [30].

In our case, the complexes of Li+ ions with maximum coordination number 2 are presented in Fig. 4, but the coordination number of ions can reach 8 [31]. Due to small radius (0.6 A), the Li+ ions are highly mobile, so they can create as well as destroy the complexes easily [29, 31], and because of that, it is difficult to define complex structure involving lithium perchlorate salt that was formed during the curing reaction.

Figure 6 presents the micrographs of reflective optical microscopes of the synthesized composites with different content of lithium perchlorate salt. The formation of ordered structures in the composites with addition of the salt into the system was observed. In this case, the reflective optical microscopy used polarized mode revealed the presence of the distributed inclusions, probably, of inorganic nature with sizes ranging from 2 to 20 μm. In order to confirm the presence of inclusions in the composites, the structural investigation that used scanning electron microscopy was conducted. The results are presented in Fig. 7. One can see the presence of the inclusions observed by ROM (for the samples with some LiClO4 content) and the increase of their number and size with the increase of LiClO4 content in the composites. In order to determine the nature of found inclusions, the elemental analysis of nine different areas of surface of the composite with 50 phr LiClO4 has been fulfilled (Fig. 8). Normalized mass distribution of elements in the microareas shown in Fig. 8 are presented in Table 2. It is evident that content of elements in spectra is different. It is important that the inclusions identified by ROM (Fig. 6) and SEM (Fig. 7) are characterized with the decreased content of carbon and the increased content of oxygen and chlorine, which enter into the composition of LiClO4 (spectra 3–5), comparing to the spectra of the polymer matrix (spectra 7–9). That can be explained by the oxygen and chlorine atom aggregation and, perhaps, also with aggregation of lithium atoms (however, it was impossible to determine such aggregation with the conducted investigations) from the lithium perchlorate salts dissolved in DEG-1 during its synthesis. The presence of a number of carbon atoms (even in the spectrum 3–5 of the inclusions) can be explained by the overlapping of their high content in macromolecular chains of polymer matrix that may partially cover the inclusions.
Fig. 6
Fig. 6

Reflective optical microscopy results. ROM of the epoxy polymer with a 0, b 10, c 20, and d 50 phr LiClO4 salt

Fig. 7
Fig. 7

Scanning electron microscopy results. SEM of the composites with a 0, b 10, c 20, and d 50 phr LiClO4 salt

Fig. 8
Fig. 8

SEM with elemental analysis. SEM of the composite with 50 phr LiClO4 surface with the appointment of elemental analysis spectra

Table 2

The mass distribution (%wt) of elements in different areas of the composite surface with 50 phr of LiClO4






Spectrum 1





Spectrum 2





Spectrum 3





Spectrum 4





Spectrum 5





Spectrum 6





Spectrum 7





Spectrum 8





Spectrum 9





The elemental composition of the initial lithium perchlorate salt was also determined. It was found that the chlorine in salt is 41.61%wt and oxygen is 58.39%wt. Lithium content could not be determined.

Summary elemental map (Fig. 9d) of the composite with 20 phr of LiClO4 was constructed from elemental maps of individual elements (carbon—Fig. 9a; oxygen—Fig. 9, b; chlorine—Fig. 9c) for determination of distribution of elements on its surface. The calculations have shown that the content of the elements on the surface of the composite are the following: carbon is 51.57 wt%, oxygen is 43.79 wt%, and chlorine is 4.64 wt%, while their distribution coincides with the ordering of inclusions identified by the means of optical and electron microscopy. This allows concluding that the nature of these inclusions with oxygen and chlorine saturation is inorganic.
Fig. 9
Fig. 9

The elemental analysis results. The elemental map of the surface of the composite with 20 phr LiClO4: a C, b O, c Cl, and the d combined map


The comprehensive study of composites based on aliphatic epoxy oligomer (DEG-1) containing different amounts of LiClO4 salt (0–50 phr) revealed creation of interactions between lithium cations Li+ and the macromolecular chain of DEG-1 with forming of coordinative complexes. It is reflected in a substantial reduction of segmental mobility of DEG-1 chains within the formed complexes that linearly increase glass transition temperature T g of polymer matrix with the salt content.

It was found that at higher temperature (200 versus 60 °C), the values of conductivity σ are three orders of magnitude higher with maximum at 15 phr of LiClO4. Such conductivity behavior is explained by existence of two opposite competitive processes, namely, the growth of salt content in composite gives the increase of carrier number and the raise of conductivity. On the other hand, the restriction of molecular movements of DEG-1 because of the forming of the coordinative complexes reduces the carrier mobility. At higher temperatures, the raising of molecular movements compensates this mechanism and conductivity becomes essentially higher.

Detailed IR spectroscopy study allowed suggesting the scheme of LiClO4 interaction with polymer chains, namely, the possible ion-dipole interactions of Li+ ion with the ether bond of polyethylene oxide fragment and OH group of the disclosed epoxy ring of DEG-1, with secondary amine group, or tertiary amine group of PEPA and ether bond simultaneously.

The results of morphological and structural studies by means of optical and electron microscopes as well as by elemental analysis have revealed the presence of inclusions with sizes from nanometers up to ~20 μm, probably, of inorganic nature distributed in the polymer matrix.



Epoxy oligomer of diglycide aliphatic ester of polyethylene glycol


Differential scanning calorimetry




Lithium perchlorate salt


Polyethylene oxide


Polyethylene polyamine


Reflective optical microscopy


Scanning electron microscopy


Solid polymer electrolytes

T g

Glass transition temperature


Transmission optical microscopy


Wide-angle X-ray spectroscopy



This work was supported by the project “Creation of new electroactive polymer composites with hybrid nanofillers based on synergism concept” carrying out in the frame of Target Complex Programme of fundamental investigations of NASU “Fundamental problems of creation of new nanomaterials and nanotechnologies.”

Authors’ contributions

LM provided the transmission and reflective optical microscopies, performed the processing and result analysis, and wrote the manuscript. MI, YeM, and AS provided the valuable discussions and the analysis of results related to the structural organization. IT performed the IR measurements and interpretation of the IR data. DV provided the WAXS and scanning electron microscopy investigations and analysis of the WAXS results. VS performed the elemental analysis. AS has made the analysis of the recent research in the field. GB and AS helped with the interpretation and joint analysis of the results obtained form various investigations. All authors read and approved the final manuscript.

Authors’ information

LM is a PhD student at the Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine (NAS of Ukraine) and at the Université de Lyon, Université Lyon 1, “Ingénierie des Matériaux Polymères,” UMR CNRS 5223, IMP@LYON1. MI is a doctor in physics, head of the Department of the E.O. Paton Electric Welding Institute of the NAS of Ukraine, and senior staff scientist at the Institute of Macromolecular Chemistry of the NAS of Ukraine. YeM is a professor, Dr. Hab. in polymer physics, leading staff scientist at the Institute of Macromolecular Chemistry of the NAS of Ukraine, and director of the Centre for Thermophysical Investigations and Analysis of the NAS of Ukraine. IT is a PhD in polymer chemistry and a researcher at the Institute of Macromolecular Chemistry of the NAS of Ukraine. DV is a PhD in polymer physics, senior staff scientist at the Institute of Macromolecular Chemistry of the NAS of Ukraine and at the E.O. Paton Electric Welding Institute of the NAS of Ukraine. VS is a researcher at the E.O. Paton Electric Welding Institute of the NAS of Ukraine. AS is a PhD in technology, staff scientist at the the E.O. Paton Electric Welding Institute of the NAS of Ukraine. GB is a Dr. Hab. in physics, director of Research CNRS, Université de Lyon, Université Lyon 1, “Ingénierie des Matériaux Polymères,” UMR CNRS 5223, IMP@LYON1.

Competing interests

The authors declare that they have no competing interests.

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Authors’ Affiliations

Institute of Macromolecular Chemistry of the NAS of Ukraine, Kharkivske shosse 48, Kyiv, 02160, Ukraine
Université de Lyon, Université Lyon 1, Ingénierie des Matériaux Polymères, UMR CNRS 5223, 15 Boulevard A. Latarjet, Villeurbanne Cedex, 69622, France
E.O. Paton Electric Welding Institute of the NAS of Ukraine, Kazymyra Malevych str. 11, Kyiv, 03680, Ukraine


  1. Sudhakar YN, Selvakumar M, Krishna BD (2013) LiClO4-doped plasticized chitosan and poly(ethylene glycol) blend as biodegradable polymer electrolyte for supercapacitors. Ionics 19:277–285View ArticleGoogle Scholar
  2. Zygadło-Monikowska E, Florjan´czyk Z, Ostrowska J, Bołtromiuk P, Frydrych J, Sadurski W, Langwald N (2011) Synthesis and characterization of new trifluoroalkoxyborates lithium salts of ionic liquid properties. Electrochim Acta 57:66–73View ArticleGoogle Scholar
  3. Bergman M, Bergfelt A, Sun B, Bowden T, Brandell D, Johansson P (2015) Graft copolymer electrolytes for high temperature Li-battery applications, using poly(methyl methacrylate) grafted poly(ethylene glycol)methyl ether methacrylate and lithium bis (trifluoromethanesulfonimide). Electrochim Acta 175:96–103View ArticleGoogle Scholar
  4. Bo C, Qiang X, Zhen H, Yanran Z, Shaojie C, Xiaoxiong X (2016) One-pot preparation of new copolymer electrolytes with tunable network structure for all-solid-state lithium battery. J Power Sources 331:322–331View ArticleGoogle Scholar
  5. Wei L, Nian L, Jie S, Po-Chun H, Yuzhang L, Hyun-Wook L, Yi C (2015) Ionic conductivity enhancement of polymer electrolytes with ceramic nanowire fillers. Nano Lett 15:2740–2745View ArticleGoogle Scholar
  6. Mohamed TA, Padmanathan N, Selladurai S (2014) Effect of nanofiller CeO2 on structural, conductivity, and dielectric behaviors of plasticized blend nanocomposite polymer electrolyte. Ionics 21:825–840Google Scholar
  7. Guilherme LA, Borges RS, Moraes EMS, Silva GG, Pimentac MA, Marletta A, Silva RA (2007) Ionic conductivity in polyethylene-b-poly(ethylene oxide)/lithium perchlorate solid polymer electrolytes. Electrochim Acta 53:1503–1511View ArticleGoogle Scholar
  8. Chai MN, Isa MIN (2012) Investigation on the conduction mechanism of carboxyl methylcellulose-oleic acid natural solid polymer electrolyte. Int J Adv Technol Eng Res 2:36–39Google Scholar
  9. Ibrahim S, Johan MR (2012) Thermolysis and conductivity studies of poly(ethylene oxide) (peo) based polymer electrolytes doped with carbon nanotube. Int J Electrochem Sci 7:2596–2615Google Scholar
  10. Ahmad Z, Isa MIN (2012) Ionics conduction via correlated barrier hoping mechanism in solid biopolymer electrolytes. Int J Latest Res Sci Technol 1:70–75Google Scholar
  11. Sharma P, Kanchan DK (2013) A comparison of effect of PEG and EC plasticizers on relaxation dynamics of PEO–PMMA–AgNO3 polymer blends. Ionics 19:1285–1290View ArticleGoogle Scholar
  12. Karan NK, Pradhan DK, Thomas R, Natesan B, Katiyar RS (2008) Solid polymer electrolytes based on polyethylene oxide and lithium trifluoro-methane sulfonate (PEO–LiCF3SO3): ionic conductivity and dielectric relaxation. Solid State Ionics 179:689–696View ArticleGoogle Scholar
  13. Kesavan K, Mathew CM, Rajendran S, Subbu C, Ulaganathan M (2015) Solid polymer blend electrolyte based on poly(ethylene oxide) and poly(vinyl pyrrolidone) for lithium secondary batteries. Braz J Phys 45:19–27View ArticleGoogle Scholar
  14. Das S, Ghosh A (2015) Ionic conductivity and dielectric permittivity of PEO-LiClO4 solid polymer electrolyte plasticized with propylene carbonate. AIP Adv 5:027125View ArticleGoogle Scholar
  15. Pradhan DK, Tripathy SN (2013) Effect of plasticizer concentration on microstructural and dielectric properties of polymer composite electrolyte. Advances Chem Sci 2:114–121Google Scholar
  16. Ar D, Karan S, De SK (2009) Effect of nanofillers on thermal and transport properties of potassium iodide polyethylene oxide solid polymer electrolyte. Solid State Commun 149:1282–1287View ArticleGoogle Scholar
  17. Zhang Y, Li J, Huo H, Jiang S (2012) Effects of lithium perchlorate on poly(ethylene oxide) spherulite morphology and spherulite growth kinetics. J Appl Polym Sci 123:1935–1943View ArticleGoogle Scholar
  18. Machado GO, Prud’homme RE, Pawlicka A (2007) Conductivity and thermal analysis studies of solid polymeric electrolytes based on plasticized hydroxyethyl cellulose. e-Polymers 115:ISSN 1618–ISSN 7229Google Scholar
  19. Kyung JL, Yong WK, Joo HK, Jong HK (2007) Supramolecular polymer/metal salt complexes containing quadruple hydrogen bonding units. J Polym Sci B Polym Phys 45:3181–3188View ArticleGoogle Scholar
  20. Anji RP, Hee-Woo R (2016) The effects of LiTDI salt and POSS-PEG (n = 4) hybrid nanoparticles on crystallinity and ionic conductivity of PEO based solid polymer electrolytes. Sci Adv Mater 8:931–940(10)View ArticleGoogle Scholar
  21. Marcinek M, Syzdek J, Marczewski M, Piszcz M, Niedzicki L, Kalita M, Plewa-Marczewska A, Bitner A, Wieczorek P, Trzeciak T, Kasprzyk M, Łężak P, Zukowska Z, Zalewska A, Wieczorek W (2015) Electrolytes for Li-ion transport—review. Solid State Ionics 276:107–126View ArticleGoogle Scholar
  22. Matkovska L, Iurzhenko M, Mamunya Y, Matkovska O, Demchenko V, Lebedev E, Boiteux G, Serghei A (2014) Electrophysical behavior of ion-conductive organic-inorganic polymer system based on aliphatic epoxy resin and salt of lithium perchlorate. Nanoscale Res Lett 9:674View ArticleGoogle Scholar
  23. Sim LH, Gan SN, Chan CH, Yahya R (2010) ATR-FTIR studies on ion interaction of lithium perchlorate in polyacrylate/poly (ethylene oxide) blends. Spectrochim Acta A Mol Biomol Spectrosc 76:287–292View ArticleGoogle Scholar
  24. Abarna S, Hirankumar G (2014) Study on new lithium ion conducting electrolyte based on polyethylene glycol-p-tertoctyl phenyl ether and lithium perchlorate. Int J ChemTech Res 6:5161–5167Google Scholar
  25. Bellamy L (1975) Infrared spectra of complex molecules. Chapman and Hall, London, p 433Google Scholar
  26. Selvasekarapandian S, Baskaran R, Kamishima O, Kawamura J, Hattori T (2006) Laser Raman and FTIR studies on Li+ interaction in PVAc–LiClO4 polymer electrolytes. Spectrochim Acta A Mol Biomol Spectrosc 65:1234–1240View ArticleGoogle Scholar
  27. Mamunya Ye, Iurzhenko M, Lebedev E, Levchenko V, Chervakov O, Matkovska O, Sverdlikovska O (2013) Electroactive polymer materials. Alpha-Reklama, Kyiv, p 402 (in Ukrainian)Google Scholar
  28. Chiu CY, Chen HW, Kuo SW, Huang CF, Chang FC (2004) Investigating the effect of miscibility on the ionic conductivity of LiClO4/PEO/PCL ternary blends. Macromolecules 37:8424–8430View ArticleGoogle Scholar
  29. Fullerton-Shirey SK, Maranas JK (2009) Effect of LiClO4 on the structure and mobility of PEO-based solid polymer electrolytes. Macromolecules 42:2142–2156View ArticleGoogle Scholar
  30. Kuo PL, Liang WJ, Chen TY (2003) Solid polymer electrolytes V: microstructure and ionic conductivity of epoxide-crosslinked polyether networks doped with LiClO4. Polymer 44:2957–2964View ArticleGoogle Scholar
  31. Olsher U, Izatt RM, Bradshaw JS, Dalley NK (1991) Coordination chemistry of lithium ion: a crystal and molecular structure review. Chem Rev 91:137–164View ArticleGoogle Scholar
  32. Nakamoto K (1986) Infrared and Raman spectra of inorganic and coordination compounds. A Wiley Interscience publication, New Jersey, p 484Google Scholar
  33. Chini M, Crotti P, Macchia F (1990) Metal salts as new catalysts for mild and efficient aminolysis of oxiranes. Tetrahedron Lett 31:4661–4664View ArticleGoogle Scholar


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