Table 4 Adsorption isotherm parameters and correlation coefficients as a function of temperature for the adsorption of Cd(II) on MBC1and MBC2
From: Investigations of Heavy Metal Ion Sorption Using Nanocomposites of Iron-Modified Biochar
System | Parameters | MBC1 | MBC2 | ||||
---|---|---|---|---|---|---|---|
Temperature [K] | |||||||
295 | 315 | 335 | 295 | 315 | 335 | ||
Langmuir | q e,exp | 37.64 | 32.50 | 26.85 | 41.33 | 39.44 | 32.52 |
q 0 | 38.00 | 35.04 | 28.08 | 41.25 | 41.68 | 32.71 | |
K L | 0.182 | 0.045 | 0.043 | 0.191 | 0.072 | 0.068 | |
R L | 0.099 | 0.310 | 0.317 | 0.095 | 0.216 | 0.227 | |
R 2 | 0.999 | 0.952 | 0.993 | 0.990 | 0.982 | 0.994 | |
Freundlich | K F | 13.06 | 9.29 | 4.49 | 13.06 | 10.76 | 6.54 |
1/n | 0.204 | 0.225 | 0.332 | 0.187 | 0.249 | 0.304 | |
R 2 | 0.976 | 0.618 | 0.794 | 0.966 | 0.627 | 0.771 | |
Temkin | A | 37.542 | 7.590 | 0.796 | 102.432 | 5.344 | 1.646 |
B | 4.103 | 4.255 | 4.974 | 3.990 | 5.660 | 5.347 | |
b T | 603.84 | 582.35 | 498.15 | 620.99 | 437.77 | 463.38 | |
R 2 | 0.983 | 0.698 | 0.917 | 0.986 | 0.631 | 0.897 |