Table 2 Specific surface area (SSA), bandgap, phase composition, and results from the photocatalytic tests using MO and RhB as model pollutants under UV and natural sunlight using TNT powders and reference TiO2 powder
Methyl orange, MO | Rhodamine B, RhB | ||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
UV | Sunlight | UV | Sunlight | ||||||||||||||||
Cat | Ph | SSA | Bandgap | R eff | C (end) | Reaction kinetics | R eff | C (end) | Reaction kinetics | R eff | C (end) | Reaction kinetics | R eff | C (end) | Reaction kinetics | ||||
m2 g−1 | eV | % | mg L−1 | κ 1 h−1 | R 2 | % | mg L−1 | κ 1 h−1 | R 2 | % | mg L−1 | κ 1 h−1 | R 2 | % | mg L−1 | κ 1 h−1 | R 2 | ||
TNT | A | 179.2 | 3.04 | 13.9 | 6.6 | 0.04 | 0.50 | 80.3 | 1.1 | 0.82 | 0.97 | 35.7 | 5.5 | 0.15 | 0.98 | 93.2 | 0.7 | 1.29 | 0.93 |
250 | A + B | 123.3 | 3.03 | 35.6 | 6.7 | 0.15 | 0.99 | 91.1 | 1.0 | 0.89 | 0.97 | 14.2 | 8.4 | 0.06 | 0.94 | 84.6 | 1.4 | 0.63 | 0.99 |
350 | A | 86.5 | 3.07 | 47.2 | 5.6 | 0.24 | 0.98 | 76.2 | 2.6 | 0.46 | 0.87 | 28.6 | 6.2 | 0.13 | 0.94 | 57.7 | 4.3 | 0.31 | 0.94 |
450 | A + B | 70.4 | 3.14 | 38.3 | 7.4 | 0.15 | 0.96 | 87.0a | 1.7 | 1.05 | 0.97 | 42.9 | 5.6 | 0.18 | 0.98 | 91.1 | 1.0 | 0.80 | 0.98 |
550 | A + R | 35.4 | 2.88 | 7.1 | 9.6 | 0.03 | 0.97 | 15.7 | 9.7 | 0.07 | 0.85 | 21.0 | 7.5 | 0.07 | 0.92 | 75.5 | 2.3 | 0.48 | 0.99 |
TiO2 | A | 10.2 | 3.18 | 97.5 | 0.3* | 2.78 | 0.89 | 95.1b | 0.4* | 3.02 | 0.98 | 96.1 | 0.2 | 1.05 | 0.99 | 97.9 | 0.2 | 1.22 | 0.89 |