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Table 2 Specific surface area (SSA), bandgap, phase composition, and results from the photocatalytic tests using MO and RhB as model pollutants under UV and natural sunlight using TNT powders and reference TiO2 powder

From: Titania nanotubes prepared by rapid breakdown anodization for photocatalytic decolorization of organic dyes under UV and natural solar light

 

Methyl orange, MO

Rhodamine B, RhB

UV

Sunlight

UV

Sunlight

Cat

Ph

SSA

Bandgap

R eff

C (end)

Reaction kinetics

R eff

C (end)

Reaction kinetics

R eff

C (end)

Reaction kinetics

R eff

C (end)

Reaction kinetics

  

m2 g−1

eV

%

mg L−1

κ 1

h−1

R 2

%

mg L−1

κ 1

h−1

R 2

%

mg L−1

κ 1

h−1

R 2

%

mg L−1

κ 1

h−1

R 2

TNT

A

179.2

3.04

13.9

6.6

0.04

0.50

80.3

1.1

0.82

0.97

35.7

5.5

0.15

0.98

93.2

0.7

1.29

0.93

250

A + B

123.3

3.03

35.6

6.7

0.15

0.99

91.1

1.0

0.89

0.97

14.2

8.4

0.06

0.94

84.6

1.4

0.63

0.99

350

A

86.5

3.07

47.2

5.6

0.24

0.98

76.2

2.6

0.46

0.87

28.6

6.2

0.13

0.94

57.7

4.3

0.31

0.94

450

A + B

70.4

3.14

38.3

7.4

0.15

0.96

87.0a

1.7

1.05

0.97

42.9

5.6

0.18

0.98

91.1

1.0

0.80

0.98

550

A + R

35.4

2.88

7.1

9.6

0.03

0.97

15.7

9.7

0.07

0.85

21.0

7.5

0.07

0.92

75.5

2.3

0.48

0.99

TiO2

A

10.2

3.18

97.5

0.3*

2.78

0.89

95.1b

0.4*

3.02

0.98

96.1

0.2

1.05

0.99

97.9

0.2

1.22

0.89

  1. Cat catalyst, Ph phase, R eff removal efficiency, A anatase, R rutile, B brookite, TiO 2 reference powder
  2. aAfter 2 h
  3. bAfter 1 h
  4. *Below the detection limit

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