Skip to main content

Skyrmion Phase in MnSi Thin Films Grown on Sapphire by a Conventional Sputtering


Topologically protected chiral skyrmions are an intriguing spin texture that has attracted much attention because of fundamental research and future spintronic applications. MnSi with a non-centrosymmetric structure is a well-known material hosting a skyrmion phase. To date, the preparation of MnSi crystals has been investigated by using special instruments with an ultrahigh vacuum chamber. Here, we introduce a facile way to grow MnSi films on a sapphire substrate using a relatively low vacuum environment of conventional magnetron sputtering. Although the as-grown MnSi films have a polycrystalline nature, a stable skyrmion phase in a broad range of temperatures and magnetic fields is observed via magnetotransport properties including phenomenological scaling analysis of the Hall resistivity contribution. Our findings provide not only a general way to prepare the materials possessing skyrmion phases but also insight into further research to stimulate more degrees of freedom in our inquisitiveness.


Topologically protected chiral skyrmions have a vortex-like nontrivial swirling spin texture, where magnetic spins stabilized by Dzyaloshinskii–Moriya interaction (DMI) align in a non-collinear manner surrounding a sphere [1]. A large DMI is generally induced in non-centrosymmetric ferromagnets, owing to the broken inversion symmetry [2]. This complex spin texture has garnered massive attention because of the intriguing physical properties for both fundamental research and possible applications in future technology [3, 4]. Compared to magnetic domain walls, skyrmion domains exhibit stable current-driven motion at remarkably low current density, enabling low-power consumption spintronic devices [5].

MnSi with a non-centrosymmetric B20 phase is an archetypal helimagnetic material hosting a skyrmionic lattice, which has been studied theoretically and experimentally for decades 6,7,8,9,10]. In the skyrmionic lattice of MnSi, spin transfer torque (STT) is observed, leading to further investigations on the injection of spin-polarized currents [5]. In particular, the skyrmion size of MnSi ranges from ~ 18 nm, which is considered small among well-known groups with skyrmion spin textures [11]. STT tends to increase significantly with reducing skyrmion size [12, 13]. Although material parameters affect the skyrmion size, DMI and ferromagnetic exchange interaction mainly contribute to determining the skyrmion size [14]. In this regard, MnSi has excellent prospects as a good candidate for applied physics.

To confirm the evident skyrmions, diverse measurement tools, such as Lorentz transmission electron microscopy, magnetic transmission soft X-ray microscopy, magnetic force microscopy, and small-angle neutron scattering, have been used 15,16,17,18]. Such microscopic tools allow direct identification of the skyrmionic lattice in real-space, but high-quality single crystals or epitaxial thin films are needed, which are grown by special instruments with a high-vacuum chamber. The other way to reveal the existence of skyrmions is to measure the magnetotransport properties and the topological Hall effect (THE), as shown in previous reports [9, 9,19,20,21]. Skyrmions can be observed even in polycrystalline samples because they are topological objects in which the topological phase is less susceptible to impurities or crystalline nature [22].

Here, we report the magnetotransport properties of polycrystalline MnSi grown by conventional sputtering. We employed X-ray diffraction (XRD) and transmission electron microscopy (TEM) to identify the single phase of MnSi crystals and their crystallinity. The magnetic transition at approximately 25 K was revealed by measuring temperature-dependent magnetization and resistance curves, where magnetoresistance data also exhibited a distinguishable shape at the border of the transition temperature. We successfully extracted the THE signal from the measured Hall resistance, and plotted contour mapping of topological Hall resistivity as a function of temperature and magnetic field. Moreover, the analysis of the anomalous Hall resistivity contribution in MnSi films implied the stabilization of the skyrmion phase in a broader range of temperatures and magnetic fields, albeit impurities and defects in the polycrystalline MnSi sample. Our findings show that the skyrmions can be observed in polycrystalline MnSi films grown by facile and inexpensive instruments, and further investigations of similar materials possessing skyrmionic lattices can be stimulated.


MnSi films were deposited on Si (001) and c-cut sapphire (Al2O3) substrates by direct current (DC)/radio frequency (RF) magnetron sputtering with a base pressure of 1.0 × 10–6 Torr. The MnSi films were grown at room temperature under 10 mTorr Ar pressure by co-sputtering Mn and Si targets for 5 min. The DC power for the Mn target was 10 to 20 W, and the RF power for the Si target was 100 W. Following the deposition of MnSi, the as-grown MnSi was crystallized by inducing an in situ annealing treatment for 2 h in the temperature range of 550–590 °C. The crystal phase and structure of the samples were examined by XRD with an X-ray source of Mo and Ag at 60 kV. The morphological characterization and chemical composition of the samples were analyzed by scanning electron microscopy (SEM), atomic force microscopy (AFM), and high-resolution transmission electron microscopy (HR-TEM) equipped with energy-dispersive spectroscopy (EDS). The magnetic and electrical properties were measured using a superconducting quantum interference device-vibrating sample magnetometer (SQUID-VSM), where the magnetic field and temperature were swept up to 50 kOe and down to 2 K, respectively.

Results and Discussion

The growth of MnSi films has been well described in previous reports with various methods [2, 9, 2,9,21,22,23,24,25]. However, most techniques to grow MnSi require specific facilities with an ultrahigh vacuum environment, while development of conventional magnetron sputtering with a relatively low base pressure has not yet been introduced. Since the lattice mismatch between the Si (001) substrate and cubic MnSi structure is estimated to be approximately 19%, we tested the optimal growth conditions of the MnSi films on Si (001) substrates. A co-sputtering method with Mn and Si targets was employed, and growth conditions such as RF power, growth temperature, and annealing treatments were minutely controlled to grow the MnSi films (Additional file 1: Table S1). Aguf et al. reported that as-deposited MnSi films were amorphous unless they were crystallized by annealing treatment [23]. Indeed, we found that the initially deposited amorphous MnSi turned into a crystallized MnSi phase after annealing treatment (Additional file 1: Fig. S1). Most results using Si (001) substrates, however, showed that mixed phases of MnSi and Mn5Si3 were observed by XRD measurements. For this reason, Si (001) substrates were replaced by Al2O3 substrates having a low lattice mismatch (~ 4.2%).

Figure 1 presents the XRD patterns of the MnSi films grown on Si (black solid line) and Al2O3 (blue and red solid lines) substrates, where the MnSi films on Si (001) and on Al2O3 #1 were deposited under the same growth conditions (15 W power for Mn, 100 W power for Si, 590 °C annealing treatment). Note that the substrate peaks were not displayed for all samples because the grazing incident X-ray diffraction technique was used. The asterisk in the figure indicates the Mn5Si3 (ICSD card no. 04–003-4114) phase. For the MnSi film on Si (001), MnSi peaks were mainly observed; in addition, five peaks matched with the Mn5Si3 phase and several unknown impurity peaks were detected. However, we found that the peaks related to the Mn5Si3 phase were suppressed and the unknown peaks disappeared for MnSi on Al2O3 #1. Furthermore, the MnSi on Al2O3 #2 sample, in which the Mn power and annealing temperature decreased to 10 W and 550 °C, respectively, showed only MnSi (ICSD card no. 04–004-7568) peaks.

Fig. 1
figure 1

XRD patterns of MnSi films on Si [(001), black solid line] and Al2O3 (blue and red solid lines) substrates. All the peaks are indexed to the cubic B20-type MnSi phase, marked with green dotted lines. The asterisks on black and blue solid lines indicate peaks from the Mn5Si3 phase

Although the as-grown MnSi on Al2O3 #2 showed a somewhat defective surface, a highly uniform and low uneven surface was observed, as shown in the SEM image of Fig. 2a and the AFM topographic image of Fig. 2b. On the 15 × 15 μm scale of the AFM image, the root-mean-squared (RMS) roughness was measured to be under 1 nm. To characterize the detailed structure and chemical composition, cross-sectional TEM analyses of as-grown MnSi on Al2O3 #2 were carried out. Figure 2c shows a representative cross-sectional TEM image of MnSi on Al2O3 #2 at the interfacial region. Note that no stacking faults or significant defects were observed. When MnSi films are grown by conventional sputtering in a relatively low vacuum chamber, it is hard to expect that MnSi grows epitaxially to the preferred direction of the surface of substrates, considering structural parameters such as lattice mismatch and chemical bonding. Our MnSi films grown on Al2O3 have a polycrystalline nature, as confirmed by XRD patterns (Fig. 1) and fast Fourier transform (FFT) of the TEM image [inset of Fig. 2c]. We examined the chemical composition of the as-grown MnSi films. As seen in the TEM-EDS mapping of Fig. 2d, the presence of only Mn and Si elements was detected in several different regions, and the atomic ratio of Mn/Si = 1:1.1 was estimated. We tested the growth rate of MnSi films by controlling the growth time. The thickness of the as-grown MnSi films showed a linear behavior for the growth time (Additional file 1: Fig. S2).

Fig. 2
figure 2

Morphological and structural characterization of MnSi film grown on Al2O3 substrate. a SEM image of the as-grown MnSi film. b AFM topographic image corresponding to a. RMS roughness is estimated to be under 1 nm. c Representative HR-TEM image of MnSi film grown on sapphire. Inset: FFT from selected area of MnSi in the HR-TEM image. d Elemental mapping of EDS of the cross-sectional MnSi film

Figure 3a shows the temperature dependence of magnetization for MnSi on Al2O3 (thickness 25 nm) measured in an out-of-plane magnetic field of 1 kOe. The magnetization dropped significantly at temperatures above 25 K, indicating a ferromagnetic transition temperature (TC), similar to bulk MnSi [26, 27]. The resistivity depending on the temperature exhibited metallic behavior above TC, as shown in Fig. 3b. Below TC, the resistivity tended to decrease with T2 dependence as the temperature decreased, owing to the coupling of charge carriers to spin fluctuations in the helimagnetic phase [28]. As seen in the inset of Fig. 3b, the derivative of resistivity versus temperature highlighted the TC of MnSi films at approximately 25 K. The polycrystals and defects on the surface give rise to a low residual resistivity ratio, i.e., [ρ(300 K)/ρ(5 K)] ~ 1.7.

Fig. 3
figure 3

a Field-cooled magnetization as a function of temperature for a 25 nm thick MnSi film in an external magnetic field of 1 kOe. b Zero-field longitudinal resistance as a function of temperature. Inset: derivative of the resistance as a function of the temperature highlighting the anomaly of magnetic transition. c Perpendicular magnetoresistance at 2, 25, and 50 K. For clarity, arbitrary offsets are added, and the magnetoresistance measured at 50 K is magnified by 10 times

Figure 3c shows the magnetoresistance for the magnetic fields perpendicular to the film plane at different temperatures of 2 K, 25 K, and 50 K. As we discussed above, since the as-grown MnSi films had a polycrystalline nature, the magnetic phase transition from the magnetoresistance was not clearly observed. In low magnetic fields, however, the temperature dependence of the magnetoresistance exhibited distinguishable features. As the temperature increased, the shape of the magnetoresistance in the vicinity of the zero magnetic field changed from flat (2 K) to sharp (25 K) and broad (50 K) peaks.

Regarding the spin-chirality-driven Hall effect, THE can be induced by DMI arising from strong spin–orbit coupling and non-centrosymmetric B20 crystal structure [29], which is considered a hallmark of the existence of the skyrmion phase. We performed Hall resistivity measurements to observe abnormal resistivity related to THE. The total Hall resistivity can be expressed as a combination of three components:

$$\begin{aligned} \rho_{{{\text{Hall}}}} & = \rho_{{{\text{normal}}}} + \rho_{{{\text{AHE}}}} + \rho_{{{\text{THE}}}} \\ & = R_{0} H + \left( {\alpha \rho_{xx0} + \beta \rho_{xx0}^{2} + b\rho_{xx}^{2} } \right)M + n_{{{\text{Skx}}}} PR_{{{\text{TH}}}} B_{{{\text{eff}}}} , \\ \end{aligned}$$

where ρnormal, ρAHE, and ρTHE are the normal, anomalous, and topological Hall resistivities, respectively. R0 is the normal Hall coefficient, and α, β, and b are the constants corresponding to the skew scattering, side jump, and intrinsic contributions to the anomalous Hall resistivity. Additionally, nSkx is the relative skyrmion density, P is the polarization of the conduction electrons, RTH is the topological Hall coefficient, and Beff is the effective magnetic field derived from the real-space Berry phase [20, 30]. The topological Hall contribution can be extracted by subtracting the normal and anomalous Hall resistivity terms from the measured total Hall resistivity.

Figure 4a shows deconvoluted Hall data to extract the THE signal at 10 K as the blue curve, including normal (green line) and anomalous (red curve) Hall resistivities. Note that the positive slope of ρnormal indicates p-type majority carriers, and ρAHE is negative, consistent with those of bulk MnSi [31], thin films [9], and nanowires [20]. ρnormal is obtained from the linear fit at high magnetic fields, and ρAHE is directly taken from the magnetization data. The ρTHE depending on the temperature is displayed in Fig. 4b. Interestingly, the sign of ρTHE flipped at the border of 25 K, where the magnetic transition was expected. The sign of ρTHE is very sensitive to the spin polarization of charge carriers. In the band structure of MnSi, the localized electrons in the d band affect the density of states near the Fermi level, while itinerant electrons in the s band contribute meagerly to the band structure [31], allowing the spin polarization to be delicate. In addition, since the spin polarization can be changed by external factors such as tensile strain and crystal purity with temperature [9], the flipped sign of ρTHE in our polycrystalline MnSi sample is reasonable. Figure 4c presents the contour mapping of ρTHE as a function of magnetic field and temperature. While the skyrmion phase in bulk MnSi was observed in a narrow temperature range close to the magnetic transition temperature, a nonzero ρTHE was collected from 2 to 40 K regardless of the sign. The absolute value of ρTHE had a maximum of 36 nΩ cm at 10 K and 4 kOe, larger than that of thin films grown by MBE (10 nΩ cm) [9], bulk (4.5 nΩ cm) [32], and nanowire (15 nΩ cm) [20] but similar to that of thin films grown by off-axis magnetron sputtering with an ultrahigh vacuum chamber [25].

Fig. 4
figure 4

a The representative Hall resistivity curve at 10 K. The THE signal (blue curve) is extracted by the subtracting normal (green line) and anomalous Hall signals (red curve) from the total measured Hall resistivity (black curve). b Topological Hall resistivities at various temperatures, extracted using the same procedure detailed in the text. c The contour mapping of the THE signal as a function of the magnetic field and temperature, constructed by interpolation of topological Hall resistivity between temperatures. d Anomalous Hall resistivity as a function of the squared longitudinal magnetoresistivity below the temperature where the topological Hall resistivity is not zero

ρAHE consists of three components: skew scattering, side jump, and intrinsic contributions. An implication in the scaling of the anomalous Hall contribution is that ρAHE is proportional to the intrinsic contribution, \(\rho_{xx}^{2}\), associated with the momentum-space Berry phase [33]. In Fig. 4d, we plot ρAHE against \(\rho_{xx}^{2}\) at 20 kOe, showing an obvious deviation from linear dependence. The breakdown of the scaling suggests that the anomalous Hall effect is relevant to extrinsic skew scattering and side jump contributions caused by impurities and defects in our polycrystalline MnSi sample, retaining the stabilization of the skyrmion phase in a broader range of temperatures and magnetic fields.


In summary, we demonstrated a method to grow MnSi films on Al2O3 by conventional magnetron sputtering with a relatively low vacuum chamber. Developing a facile way to fabricate various nanostructures is imperative [34, 35]. The spectroscopic and morphological analyses confirmed that the as-deposited MnSi films have a polycrystalline nature with a highly uniform and low roughness surface. The transport properties exhibit the intrinsic characteristics of MnSi, although the magnetic transition temperature was slightly lower than that of previous results. More importantly, we observe a stable skyrmion phase in a broad range of temperatures and magnetic fields, even in our polycrystalline MnSi films, attributed to the complicated implication of the Hall resistivity contribution. This work opens up the opportunity for extensive investigation of materials possessing skyrmion phases beyond the burden of preparing single crystals or epitaxial thin films.

Availability of data and materials

All data generated or analyzed during this study are included in this published article and its supplementary information files, and are available from corresponding author on reasonable request.



Dzyaloshinskii–Moriya interaction


Spin transfer torque


Topological Hall effect


X-ray diffraction


Transmission electron microscope

Al2O3 :



Direct current


Radio frequency


Scanning electron microscopy


Atomic force microscopy


High-resolution transmission electron microscopy


Energy-dispersive spectroscopy


Superconducting quantum interference device-vibrating sample magnetometer




Fast Fourier transform

T C :

Ferromagnetic transition temperature


  1. Roszler UK, Bogdanov AN, Pfleiderer C (2006) Spontaneous skyrmion ground states in magnetic metals. Nature 442:797–801

    Article  Google Scholar 

  2. Schroeter D, Steinki N, Schilling M, Fernández Scarioni A, Krzysteczko P, Dziomba T, Schumacher HW, Menzel D, Süllow S (2018) MnSi nanostructures obtained from epitaxially grown thin films: magnetotransport and Hall effect. J Phys: Condens Matter 20:235805

    Google Scholar 

  3. Schulz T, Ritz R, Bauer A, Halder M, Wagner M, Franz C, Pfleiderer C, Everschor K, Garst M, Rosch A (2012) Emergent electrodynamics of skyrmions in a chiral magnet. Nat Phys 8:301–304

    CAS  Article  Google Scholar 

  4. Fert A, Cros V, Sampaio J (2013) Skymions on the track. Nat Nanotechnol 8:152–156

    CAS  Article  Google Scholar 

  5. Jonietz F, Mühlbauer S, Pfleiderer C, Neubauer A, Münzer W, Bauer A, Adams T, Georgii R, Böni P, Duine RA, Everschor K, Garst M, Rosch A (2010) Spin transfer torques in MnSi at ultralow current densities. Science 330:1648–1651

    CAS  Article  Google Scholar 

  6. Lonzarich GG, Taillefer L (1985) Effect of spin fluctuations on the magnetic equation of state of ferromagnetic or nearly ferromagnetic metals. J Phys C: Solid State Phys 18:4339–4371

    CAS  Article  Google Scholar 

  7. Magnano E, Bondino F, Cepek C, Parmigiani F, Mozzati MC (2010) Ferromagnetic and ordered MnSi (111) epitaxial layers. Appl Phys Lett 96:152503

    Article  Google Scholar 

  8. Tonomura A, Yu XZ, Yanagisawa K, Matsuda T, Onose Y, Kanazawa N, Park HS, Tokura Y (2012) Real-space observation of skyrmion lattice in helimagnet MnSi thin samples. Nano Lett 12:1673–1677

    CAS  Article  Google Scholar 

  9. Li Y, Kanazawa N, Yu XZ, Tsukazaki A, Kawasaki M, Ichikawa M, Jin XF, Kagawa F, Tokura Y (2013) Robust formation of skyrmions and topological Hall effect anomaly in epitaxial thin films of MnSi. Phys Rev Lett 110:117202

    Article  Google Scholar 

  10. Zhang SL, Chalasani R, Baker AA, Steinke NJ, Figueroa AI, Kohn A, van der Laan G, Hesjedal T (2016) Engineering helimagnetism in MnSi thin films. AIP Adv 6:015217

    Article  Google Scholar 

  11. Yu X, DeGrave JP, Hara Y, Hara T, Jin S, Tokura Y (2013) Observation of the magnetic skyrmion lattice in a MnSi nanowire by Lorentz TEM. Nano Lett 13:3755–3759

    CAS  Article  Google Scholar 

  12. Bisig A, Akosa CA, Moon JH, Rhensius J, Moutafis C, von Bieren A, Heidler J, Kiliani G, Kammerer M, Curcic M, Weigand M, Tyliszczak T, van Waeyenberge B, Stoll H, Schutz G, Lee KJ, Manchon A, Kläui M (2016) Enhanced nonadiabaticity in vortex cores due to the emergent Hall effect. Phys Rev Lett 117:277203

    Article  Google Scholar 

  13. Ndiaye PB, Akosa CA, Manchon A (2017) Topological Hall and spin Hall effects in disordered skyrmionic textures. Phys Rev B 95:064426

    Article  Google Scholar 

  14. Wang XS, Yuan HY, Wang XR (2018) A theory on skyrmion size. Commun Phys 1:31

    Article  Google Scholar 

  15. Yu XZ, Kanazawa N, Zhang WZ, Nagai T, Hara T, Kimoto K, Matsui Y, Onose Y, Tokura Y (2012) Skyrmion flow near room temperature in an ultralow current density. Nat Commun 3:988

    CAS  Article  Google Scholar 

  16. Woo S, Song KM, Han HS, Jung MS, Im MY, Lee KS, Song KS, Fischer P, Hong JI, Choi JW, Min BC, Koo HC, Chang J (2017) Spin-orbit torque-driven skyrmion dynamics revealed by time-resolved X-ray microscopy. Nat Commun 8:15573

    CAS  Article  Google Scholar 

  17. Milde P, Köhler D, Seidel J, Eng LM, Bauer A, Chacon A, Kindervater J, Mühlbauer S, Pfleiderer C, Buhrandt S, Schütte C, Rosch A (2018) Unwinding of a skyrmion lattice by magnetic monopoles. Science 340:1076–1080

    Article  Google Scholar 

  18. Nakajima T, Oike H, Kikkawa A, Gilbert EP, Booth N, Kakurai K, Taguchi Y, Tokura Y, Kagawa F, Arima T (2017) Skymion lattice structural transition in MnSi. Sci Adv 3:e1602562

    Article  Google Scholar 

  19. Du H, Degrave JP, Xue F, Liang D, Ning W, Yang J, Tian M, Zhang Y, Jin S (2014) Highly stable skyrmion state in helimagnetic MnSi nanowires. Nano Lett 14:2026–2032

    CAS  Article  Google Scholar 

  20. Liang D, DeGrave JP, Stolt MJ, Tokura Y, Jin S (2015) Current-driven dynamics of skyrmions stabilized in MnSi nanowires revealed by topological Hall effect. Nat Commun 6:8217

    CAS  Article  Google Scholar 

  21. Menzel D, Schroeter D, Steinki N, Süllow S, Fernández Scarioni A, Schumacher HW, Okuyama H, Hidaka H, Amitsuka H (2019) Hall effect and resistivity in epitaxial MnSi thin films under ambient and high pressure. IEEE Trans Magn 55:1500204

    Article  Google Scholar 

  22. Qian F, Feng J, Fan J, Ling L, Ji Y, Liu Y, Shi Y, Miao X, Shi D, Yang H (2019) Identifying magnetic skyrmions in polycrystalline MnSi via magnetometry. Mater Lett 257:126714

    CAS  Article  Google Scholar 

  23. Aguf V, Pelleg J, Sinder M (2015) A note on the reaction between sputter co-deposited Mn and Si and formation of the MnSi phase. AIP Adv 5:067124

    Article  Google Scholar 

  24. Wilson MN, Karhu EA, Quigley AS, Rößler UK, Butenko AB, Bogdanov AN, Roberson MD, Monchesky TL (2012) Extended elliptic skyrmion gratings in epitaxial MnSi thin films. Phys Rev B 86:144420

    Article  Google Scholar 

  25. López-López J, Gomez-Perez JM, Álvarez A, Vasili HB, Komarek AC, Hueso LE, Casanova F, Blanco-Canosa S (2019) Spin fluctuations, geometrical size effects, and zero-field topological order in textured MnSi thin films. Phys Rev B 99:144427

    Article  Google Scholar 

  26. Mühlbauer S, Binz B, Jonietz F, Pfleiderer C, Rosch A, Neubauer A, Georgii R, Boni P (2009) Skymion lattice in a chiral magnet. Science 323:915–919

    Article  Google Scholar 

  27. Karhu E, Kahwaji S, Monchesky TL, Parsons C, Robertson MD, Maunders C (2010) Structure and magnetic properties of MnSi epitaxial thin films. Phys Rev B 82:184417

    Article  Google Scholar 

  28. Moriya T (1985) Spin fluctuations in itinerant electron magnetism. Springer-Verlag, Berlin

    Book  Google Scholar 

  29. Leroux M, Stolt MJ, Jin S, Pete DV, Reichhardt C, Maiorov B (2018) Skymion lattice topological Hall effect near room temperature. Sci Rep 8:15510

    Article  Google Scholar 

  30. Nagaosa N, Sinova J, Onoda S, MacDonald AH, Ong NP (2009) Anomalous Hall effect Rev Mod Phys 82:1539–1592

    Article  Google Scholar 

  31. Lee M, Kang W, Onose Y, Tokura Y, Ong NP (2009) Unusual Hall effect anomaly in MnSi under pressure. Phys Rev Lett 102:186601

    Article  Google Scholar 

  32. Neubauer A, Pfleiderer C, Binz B, Rosch A, Ritz R, Niklowitz PG, Böni P (2009) Topological Hall effect in the A phase of MnSi. Phys Rev Lett 102:186602

    CAS  Article  Google Scholar 

  33. Hou D, Su G, Tian Y, Jin X, Yang SA, Niu Q (2015) Multivariable scaling for the anomalous Hall effect. Phys Rev Lett 114:217203

    Article  Google Scholar 

  34. Leung KCF, Li XB, Li X, Lee SF, Yu JC, Mendes PM, Hermann KE, Van Hove MA (2019) Mater Chem Front 3:1555–1564

    CAS  Article  Google Scholar 

  35. Tang S, Li X, Xiao X, Zhang X, Cui Q (2020) Effects of NH3 flow rate on the growth mechanism and optical properties of InN crystallites fabricated by chemical vapor deposition. Cryst Growth Des 20:4928–4934

    CAS  Article  Google Scholar 

Download references


Not applicable .


This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (Nos. 2016R1E1A1A01942649, 2018R1D1A1B07048109, and 2020R1A2C3008044).

Author information

Authors and Affiliations



S.L. and M.H.J conceived the idea and designed the experiments. W.Y.C. and H.W.B. grew the MnSi thin films on Al2O3 substrate. S.H.C. and S.L. performed spectroscopic and morphological measurements and analyses. W.Y.C., H.W.B. and M.H.J carried out the magnetometric and transport measurements. The manuscript was written by W.Y.C., S.L. and M.H.J. with input from all authors. All authors read and approved the final manuscript.

Corresponding authors

Correspondence to Sunghun Lee or Myung-Hwa Jung.

Ethics declarations

Competing interests

The authors declare that they have no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Additional file 1:

Supplementary information.

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Choi, WY., Bang, HW., Chun, SH. et al. Skyrmion Phase in MnSi Thin Films Grown on Sapphire by a Conventional Sputtering. Nanoscale Res Lett 16, 7 (2021).

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI:


  • MnSi
  • Sputtering
  • Polycrystal
  • Skyrmion
  • Topological Hall effect